Contrasting response of monazite and zircon to a high-T thermal overprint     

Christopher R.M. McFarlane  James N. Connelly  William D. Carlson 《Lithos》2006,88(1-4):135-149

Contact metamorphism in the aureole of the 1322 Ma Makhavinekh Lake Pluton, northern Labrador, affected monazite and zircon in the adjacent 1850 Ma metapelitic gneisses. Transformation of regional garnet and sillimanite to lower-pressure symplectitic intergrowths of cordierite, orthopyroxene, and spinel was accompanied by resorption of inherited monazite inclusions in garnet coupled with the appearance of coronitic high-Y monazite rims. In situ ion-microprobe dating is used to show that high-Y rims formed during contact metamorphism. Liberation of Y and HREE from garnet also gave rise to new xenotime growth. The coronitic nature of monazite overgrowths reflects the diffusion-controlled nature of net-transfer reactions whereas its higher Y composition reflects equilibration with xenotime at peak T (> 800 °C) conditions in the inner aureole. Very thin overgrowths on inherited zircon were also encountered, but only where zircon is surrounded by the symplectitic assemblage, reflecting liberation of Zr from garnet. Although these overgrowths are too thin to date using conventional ion-microprobe techniques, well-developed triple junctions between zircon and orthopyroxene suggests that they grew in textural equilibrium with the contact metamorphic assemblage.

In contrast to monazite, inherited zircon remained intact during contact metamorphism, exhibiting no change in morphology (other than the growth of thin rims) or internal zoning throughout the aureole. However, inherited sector-zoned zircons of anatectic origin display evidence for intracrystalline Pb redistribution in the inner aureole. In these samples, ion-microprobe analyses encountered heterogeneous Pb signals and a dispersion of ²⁰⁷Pb / ²⁰⁶Pb dates away from the well constrained 1850 Ma age of regional metamorphism. Whereas analyses from the outer aureole faithfully record the age of regional metamorphism, those from the inner aureole are normally and reversely discordant and distributed along a line collinear with a 1850 to 1322 Ma discordia. This disturbance is correlated with proximity to the pluton implying that Pb was mobile in the zircon lattice during contact metamorphism. Most grains are characterized by apparent Pb loss from low-U domains and apparent Pb gain in higher-U domains. These data are interpreted to reflect recovery of strained crystalline domains leading to expulsion of Pb* that was able to efficiently diffuse into higher-U domains that were partly amorphous prior to rapid reheating in the inner aureole.  相似文献   

Morphology and stratigraphy of the late Quaternary lower Brazos valley: Implications for paleo-climate, discharge and sediment delivery     

Dennis A. Sylvia  William E. Galloway   《Sedimentary Geology》2006,190(1-4):159-175

A shallow coring and geophysical logging program has recorded the sedimentary fill of the Brazos River valley in the Texas Gulf Coastal Plain. Thermoluminescence dates together with new and recalibrated published radiocarbon dates show the valley fill to include extensive, sandy, buried falling stage and lowstand Oxygen Isotope Stage (OIS) 3 and 2 deposits. These alluvial deposits are punctuated by numerous paleosoil horizons that record alternating periods of cutting, bypass and accumulation. Maximum valley incision and two periods of terrace formation preceded marine lowstand conditions, suggesting significant discordance between preserved fluvial and classical marine system tracts. The latest Pleistocene incision and fill history appears related to cycles of increased discharge and incision, followed by system equilibration and terrace formation. Analysis of the Brazos River incised valley and its contained paleochannels indicates that latest Pleistocene mean annual discharge was as much as four times greater than that of today. This magnitude of discharge in the Brazos would require a two-fold increase in precipitation across the drainage basin. Such an increase is comparable to the present day measured positive El Niño winter precipitation anomaly across the region. Paleochannel geometries and the stratigraphic and sedimentologic data from this investigation support the hypothesis that periods of high-amplitude, El Niño-like climatic perturbations characterized the late Quaternary climate of the south-central and southwestern U.S. This period of high discharge coincides, at least in part, with late OIS 3 progradation of the Brazos delta to the shelf margin, OIS 3 and 2 valley incision across the Texas shelf, and concomitant sand bypass to intraslope basins beyond the shelf edge.  相似文献   

Radiometric ages of the Fire Clay tonstein [Pennsylvanian (Upper Carboniferous), Westphalian, Duckmantian]: A comparison of U–Pb zircon single-crystal ages and Ar/Ar sanidine single-crystal plateau ages     

Paul C. Lyons  T.E. Krogh  Y.Y. Kwok  Donald W. Davis  William F. Outerbridge  Howard T. Evans  Jr.   《International Journal of Coal Geology》2006,67(4):259-266

The Fire Clay tonstein [Pennsylvanian (Upper Carboniferous), Westphalian Series, Duckmantian Stage]–a kaolinized, volcanic-ash deposit occurring in Kentucky, West Virginia, Tennessee, and Virginia–is the most widespread bed in the Middle Pennsylvanian of the central Appalachian basin, USA. A concordant single-crystal U–Pb zircon datum for this tonstein gives a ²⁰⁶Pb/²³⁸U age of 314.6 ± 0.9 Ma (2σ). This age is in approximate agreement with a mean sanidine plateau age of 311.5 ± 1.3 Ma (1σ, n = 11) for the Fire Clay tonstein. The difference between the two ages may be due to bias between the ⁴⁰K and ²³⁸U decay constants and other factors. The age of the Fire Clay tonstein has important implications for Duckmantian Stage (Westphalian Series) sedimentation rates, correlations with the Westphalian Series of Europe, Middle Pennsylvanian volcanic events, and the late Paleozoic time scale.  相似文献   

Effect of oxidation potential and zinc sulphate on the separation of chalcopyrite from pyrite     

Shuhua He  William Skinner  Daniel Fornasiero   《International Journal of Mineral Processing》2006,80(2-4):169-176

The effects of oxidation potential (Eh) and zinc sulphate on the separation of chalcopyrite from pyrite were investigated at pH 9.0. The flotation recovery of these minerals is Eh dependent with maximum separation obtained at 275 mV SHE. Zinc sulphate addition improved this mineral separation at an Eh value of 275 mV by selectively depressing pyrite flotation. A different result was obtained at lower Eh values where zinc sulphate addition improved chalcopyrite flotation but had no or little effect on pyrite flotation. These opposite effects of zinc sulphate on mineral flotation were reconciled by examining the surface species of these minerals. The selective depression of pyrite flotation by zinc sulphate was also confirmed in the flotation of two copper ores.  相似文献   

Mapcurves: a quantitative method for comparing categorical maps   总被引：2，自引：0，他引：2  

William W. Hargrove  Forrest M. Hoffman  Paul F. Hessburg 《Journal of Geographical Systems》2006,8(2):187-208

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Development of a Speech-Based Augmented Reality System to Support Exploration of Cityscape     

Phil J. Bartie  William A. Mackaness 《Transactions in GIS》2006,10(1):63-86

When people explore new environments they often use landmarks as reference points to help navigate and orientate themselves. This research paper examines how spatial datasets can be used to build a system for use in an urban environment which functions as a city guide, announcing Features of Interest (FoI) as they become visible to the user (not just proximal), as the user moves freely around the city. Visibility calculations for the FoIs were pre‐calculated based on a digital surface model derived from LIDAR (Light Detection and Ranging) data. The results were stored in a text‐based relational database management system (RDBMS) for rapid retrieval. All interaction between the user and the system was via a speech‐based interface, allowing the user to record and request further information on any of the announced FoI. A prototype system, called Edinburgh Augmented Reality System (EARS), was designed, implemented and field tested in order to assess the effectiveness of these ideas. The application proved to be an innovative, ‘non‐invasive’ approach to augmenting the user's reality.  相似文献   

Air-sea Interaction of Typhoon Sinlaku （2002） Simulated by the Canadian MC2 Model   总被引：4，自引：1，他引：4  

任雪娟 《大气科学进展》2006,23(4):521-530

Three experiments for the simulation of typhoon Sinlaku (2002) over the western North Pacific are performed in this study by using the Canadian Mesoscale Compressible Community (MC2) atmospheric model. The objective of these simulations is to investigate the air-sea interaction during extreme weather conditions, and to determine the sensitivity of the typhoon evolution to the sea surface temperature (SST)cooling induced by the typhoon. It is shown from the three experiments that the surface heat fluxes have a substantial influence on the slow-moving cyclone over its lifetime. When the SST in the East China coastal ocean becomes 1℃ cooler in the simulation, less latent heat and sensible heat fluxes from the underlying ocean to the cyclone tend to reduce the typhoon intensity. The cyclone is weakened by 7 hPa at the time of its peak intensity. The SST cooling also has impacts on the vertical structure of the typhoon by weakening the warm core and drying the eye wall. With a finer horizontal resolution of (1/6)°×(1/6)°, the model produces higher surface wind, and therefore more surface heat fluxes are emitted from the ocean surface to the cyclone, in the finer-resolution MC2 grid compared with the relatively lower resolution of 0.25°×0.25°MC2 grid.  相似文献   

大学英语等级考试的信度与效度测试:英语四、六级与有效交际能力     

余郑璟 《成都信息工程学院学报》2002,17(2):138-148

关于大学英语四、六级,及其英语口语考试,是否具有科学的信度与效度这一问题的论证,引起了诸多争议。运用Carl Popper的反证法,在怀疑并否定其具有科学信度与效度方面,也不乏许多挑战权威的例子。尽管现今反证的理论与例证并不十分系统,但它终将会以科学的信度与效度为目标而日臻完善。  相似文献   

Influence of fracture anisotropy on ground water ages and chemistry,Valley and Ridge province,Pennsylvania   总被引：5，自引：0，他引：5  

Burton WC  Plummer LN  Busenberg E  Lindsey BD  Gburek WJ 《Ground water》2002,40(3):242-257

Model ground water ages based on chlorofluorocarbons (CFCs) and tritium/helium-3 (³H/³He) data were obtained from two arrays of nested piezometers located on the north limb of an anticline in fractured sedimentary rocks in the Valley and Ridge geologic province of Pennsylvania. The fracture geometry of the gently east plunging fold is very regular and consists predominately of south dipping to subhorizontal to north dipping bedding-plane parting and east striking, steeply dipping axial-plane spaced cleavage. In the area of the piezometer arrays, which trend north-south on the north limb of the fold, north dipping bedding-plane parting is a more dominant fracture set than is steeply south dipping axial-plane cleavage. The dating of ground water from the piezometer arrays reveals that ground water traveling along paths parallel to the dip direction of bedding-plane parting has younger ³H/³He and CFC model ages, or a greater component of young water, than does ground water traveling along paths opposite to the dip direction. In predominantly unmixed samples there is a strong positive correlation between age of the young fraction of water and dissolved sodium concentration. The travel times inferred from the model ages are significantly longer than those previously calculated by a ground water flow model, which assumed isotropically fractured layers parallel to topography. A revised model factors in the directional anisotropy to produce longer travel times. Ground water travel times in the watershed therefore appear to be more influenced by anisotropic fracture geometry than previously realized. This could have significant implications for ground water models in other areas underlain by similarly tilted or folded sedimentary rock, such as elsewhere in the Valley and Ridge or the early Mesozoic basins.  相似文献   

Analysis of a vertical dipole tracer test in highly fractured rock   总被引：1，自引：0，他引：1  

Sanford WE  Cook PG  Dighton JC 《Ground water》2002,40(5):535-542

The results of a vertical dipole tracer experiment performed in highly fractured rocks of the Clare Valley, South Australia, are presented. The injection and withdrawal piezometers were both screened over 3 m and were separated by 6 m (midpoint to midpoint). Due to the long screen length, several fracture sets were intersected, some of which do not connect the two piezometers. Dissolved helium and bromide were injected into the dipole flow field for 75 minutes, followed by an additional 510 minutes of flushing. The breakthrough of helium was retarded relative to bromide, as was expected due to the greater aqueous diffusion coefficient of helium. Also, only -25% of the total mass injected of both tracers was recovered. Modeling of the tracer transport was accomplished using an analytical one-dimensional flow and transport model for flow through a fracture with diffusion into the matrix. The assumptions made include: streamlines connecting the injection and withdrawal point can be modeled as a dipole of equal strength, flow along each streamline is one dimensional, and there is a constant Peclet number for each streamline. In contrast to many other field tracer studies performed in fractured rock, the actual travel length between piezometers was not known. Modeling was accomplished by fitting the characteristics of the tracer breakthrough curves (BTCs), such as arrival times of the peak concentration and the center of mass. The important steps were to determine the fracture aperture (240 microm) based on the parameters that influence the rate of matrix diffusion (this controls the arrival time of the peak concentration); estimating the travel distance (11 m) by fitting the time of arrival of the centers of mass of the tracers; and estimating fracture dispersivity (0.5 m) by fitting the times that the inflection points occurred on the front and back limbs of the BTCs. This method works even though there was dilution in the withdrawal well, the amount of which can be estimated by determining the value that the modeled concentrations need to be reduced to fit the data (approximately 50%). The use of two tracers with different diffusion coefficients was not necessary, but it provides important checks in the modeling process because the apparent retardation between the two tracers is evidence of matrix diffusion and the BTCs of both tracers need to be accurately modeled by the best fit parameters.  相似文献